The best way to chrome plate something might be to
take it to a chrome plating shop. The industry is
very 'job shop' oriented, with experienced people
ready to handle your parts. Before thinking
seriously about doing it yourself, here are a few
things to consider:
Regulations
Electroplating was our nation's very
first categorically regulated industry. So, what
does "categorically regulated" mean? It means that
all of the waste products from this industry --
even very dilute rinse water -- are, as a matter of
law, regulated, even if the particular substance is
so dilute that it is actually harmless. Mix the
waste in with other waste, and the whole mass is by
law hazardous waste (see EPA 'mixture rule'). Make
another product from it and (with some exception)
the product is hazardous waste (see EPA 'derived
from' rule).
In turn this means you can't discharge a drop of
hose water without pretreatment and permits; it
means you can't take your bad solution anywhere
without hazardous waste manifesting; it means you
can't accumulate it without permits either.
Finally, it means you are legally responsible for
it forever regardless of how much you spend to get
rid of it.
But are you subject to these regulations? If you
are selling plated parts or plating services,
absolutely! See EPA CFR431 and try to find an
exception -- you won't. If you are doing it solely
as a hobby, maybe you can get away with it if you
stay lucky. But if the sewer authority wants to
impose an assessment for upgrading the piping, and
your neighbors know that you are plating, they will
probably turn you in in a heartbeat. Read the fine
print on your sewer agreement: you're forbidden
from putting these wastes down the drain and both
your neighbors and the sewer authority would dearly
love for you to have to bear the cost of repairs or
upgrades. Is it likely to happen? Probably not. Can
it happen? Yes.
Chromic Acid
Chrome plating is done in very
highly concentrated (about 32 oz./gal) chromic
acid, H2CrO4 -- "hexavalent chromium" -- the stuff
that made
Erin Brockovich a household
word. If a neighborhood child develops cancer
from any cause whatsoever and his/her parents
find out that you were chrome plating, God
help you. Factories that use this stuff
require exhaust scrubbing, they require fume
suppressants that are monitored every day. The
workers require medical surveillance (frequent
blood tests for absorbed chromium).
If you do illegally dispose of chromic acid you
will probably be caught because it leaches through
the ground very readily and turns up in the
aquifer, and it is not only easily detectable but
it's visible at 1 part in a million, and all wells
and water supplies are monitored for chrome.
Dropped a beaker on the garage floor? That could be
enough to poison all of the wells for a few city
blocks in every direction, and you do not have
"pollution insurance" in your homeowner's policy.
On top of all this, many city councils have a
written or de facto ban on chrome plating. Finally,
chrome plating is notorious for hydrogen
embrittlement. If you don't know how to immediately
and properly bake the parts to relieve the
embrittlement, you can turn hardened steel parts
like springs, steering linkage, and fasteners into
brittle glass.